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- Colas, KilianStockholms universitet,Institutionen för organisk kemi (author)
Intermolecular Pummerer Coupling with Carbon Nucleophiles in Non-Electrophilic Media
- Article/chapterEnglish2017
Publisher, publication year, extent ...
- 2017-11-15
- Wiley-VCH Verlagsgesellschaft,2017
- electronicrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:su-150977
- https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-150977URI
- https://doi.org/10.1002/anie.201709715DOI
Supplementary language notes
- Language:English
- Summary in:English
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Notes
- A new Pummerer-type C-C coupling protocol is introduced based on turbo-organomagnesium amides, which unlike traditional Pummerer reactions, does not require strong electrophilic activators, engages a broad range of C(sp(3))-, C(sp(2))-, and C(sp)-nucleophiles, and seamlessly integrates with C-H and C-X magnesiation. Given the central character of sulfur compounds in organic chemistry, this protocol allows access to unrelated carbonyls, olefins, organometallics, halides, and boronic esters through a single strategy.
Subject headings and genre
- NATURVETENSKAP Kemi Organisk kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences Organic Chemistry hsv//eng
- C-C coupling
- magnesium
- main group elements
- Pummerer reaction
- sulfur
- organisk kemi
- Organic Chemistry
Added entries (persons, corporate bodies, meetings, titles ...)
- Martín-Montero, RaúlStockholms universitet,Institutionen för organisk kemi (author)
- Mendoza, AbrahamStockholms universitet,Institutionen för organisk kemi(Swepub:su)amend (author)
- Stockholms universitetInstitutionen för organisk kemi (creator_code:org_t)
Related titles
- In:Angewandte Chemie International Edition: Wiley-VCH Verlagsgesellschaft56:50, s. 16042-160461433-78511521-3773
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