Bifunctional Performance of Flow Assisted Rechargeable Iron-Air Alkaline Batteries

• Low cost rechargeable iron-air alkaline batteries have all essential attributes to adapt for large scale energy storage applications. To actualize this implementation needs to overcome the challenges including poor efficiency and short cycle lifetime. Herein, suitable synthesized catalysts for the air electrode were investigated prior to iron-air cell testing. NiCo2O4 as sole catalyst proved exceptional bifunctional OER/ORR activity and stability over 440 h operation in air. This catalyst fitted into an electrolyte and oxygen flow assisted rechargeable iron-air prototype and performed stable over 588 h and had an energy density of 377 Wh kg-1 Fe. Inadequate coulombic efficiencies of 75 – 85% and energy efficiencies around 50% hurt the performance of the cell though and needed further development. Nevertheless, the findings in this work reports the opportunities and obstacles of the rechargeable iron-air battery.

Ämnesord

NATURVETENSKAP  -- Kemi -- Materialkemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Materials Chemistry (hsv//eng)

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

Nyckelord

Inorganic Chemistry

oorganisk kemi

Publikations- och innehållstyp

vet (ämneskategori)

ovr (ämneskategori)