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Serpentinization :
Serpentinization : Connecting Geochemistry, Ancient Metabolism and Industrial Hydrogenation
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- Preiner, Martina (författare)
- Univ Dusseldorf, Inst Mol Evolut, D-40225 Dusseldorf, Germany
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- Xavier, Joana C. (författare)
- Univ Dusseldorf, Inst Mol Evolut, D-40225 Dusseldorf, Germany
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- Sousa, Filipa L. (författare)
- Univ Vienna, Dept Ecogenom & Syst Biol, Div Archaea Biol & Ecogen, Althanstr 14 UZA I, A-1090 Vienna, Austria
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- Zimorski, Verena (författare)
- Univ Dusseldorf, Inst Mol Evolut, D-40225 Dusseldorf, Germany
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- Neubeck, Anna (författare)
- Uppsala universitet,Paleobiologi
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- Lang, Susan Q. (författare)
- Univ South Carolina, Sch Earth Ocean & Environm, 701 Sumter St EWS 401, Columbia, SC 29208 USA
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- Greenwell, H. Chris (författare)
- Univ Durham, Dept Earth Sci, South Rd, Durham DH1 3LE, England
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- Kleinermanns, Karl (författare)
- Univ Dusseldorf, Inst Phys Chem, D-40225 Dusseldorf, Germany
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- Tüysüz, Harun (författare)
- Max Planck Inst Kohlenforsch, Kaiser Wilhelm Pl 1, D-45470 Mulheim, Germany
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- McCollom, Tom M. (författare)
- Univ Colorado, Lab Atmospher & Space Phys, Boulder, CO 80309 USA
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- Holm, Nils G. (författare)
- Stockholms universitet,Institutionen för geologiska vetenskaper,Stockholm Univ, Dept Geol Sci, SE-10691 Stockholm, Sweden
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- Martin, William F. (författare)
- Univ Dusseldorf, Inst Mol Evolut, D-40225 Dusseldorf, Germany
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(creator_code:org_t)
- 2018-09-22
- 2018
- Engelska.
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Ingår i: Life. - : MDPI AG. - 2075-1729.
- Relaterad länk:
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https://doi.org/10.3...
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https://www.mdpi.com...
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https://uu.diva-port... (primary) (Raw object)
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https://urn.kb.se/re...
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https://doi.org/10.3...
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https://urn.kb.se/re...
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Abstract
Ämnesord
Stäng
- Rock-water-carbon interactions germane to serpentinization in hydrothermal vents have occurred for over 4 billion years, ever since there was liquid water on Earth. Serpentinization converts iron(II) containing minerals and water to magnetite (Fe3O4) plus H-2. The hydrogen can generate native metals such as awaruite (Ni3Fe), a common serpentinization product. Awaruite catalyzes the synthesis of methane from H-2 and CO2 under hydrothermal conditions. Native iron and nickel catalyze the synthesis of formate, methanol, acetate, and pyruvate-intermediates of the acetyl-CoA pathway, the most ancient pathway of CO2 fixation. Carbon monoxide dehydrogenase (CODH) is central to the pathway and employs Ni-0 in its catalytic mechanism. CODH has been conserved during 4 billion years of evolution as a relic of the natural CO2-reducing catalyst at the onset of biochemistry. The carbide-containing active site of nitrogenase-the only enzyme on Earth that reduces N(2)is probably also a relic, a biological reconstruction of the naturally occurring inorganic catalyst that generated primordial organic nitrogen. Serpentinization generates Fe3O4 and H-2, the catalyst and reductant for industrial CO2 hydrogenation and for N-2 reduction via the Haber-Bosch process. In both industrial processes, an Fe3O4 catalyst is matured via H-2-dependent reduction to generate Fe5C2 and Fe2N respectively. Whether serpentinization entails similar catalyst maturation is not known. We suggest that at the onset of life, essential reactions leading to reduced carbon and reduced nitrogen occurred with catalysts that were synthesized during the serpentinization process, connecting the chemistry of life and Earth to industrial chemistry in unexpected ways.
Ämnesord
- NATURVETENSKAP -- Biologi (hsv//swe)
- NATURAL SCIENCES -- Biological Sciences (hsv//eng)
- NATURVETENSKAP -- Geovetenskap och miljövetenskap (hsv//swe)
- NATURAL SCIENCES -- Earth and Related Environmental Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Nyckelord
- rock-water-carbon interactions
- origin of life
- carbides
- iron sulfur
- early metabolism
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Preiner, Martina
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Xavier, Joana C.
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Sousa, Filipa L.
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Zimorski, Verena
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Neubeck, Anna
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Lang, Susan Q.
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visa fler...
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Greenwell, H. Ch ...
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Kleinermanns, Ka ...
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Tüysüz, Harun
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McCollom, Tom M.
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Holm, Nils G.
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Martin, William ...
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