WFRF:(Li Man Bo)
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Silver-Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions
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- Li, Man-Bo (author)
- Stockholms universitet,Institutionen för organisk kemi,Anhui University, P. R. China,Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China.;Stockholm Univ, Arrhenius Lab, Dept Organ Chem, S-10691 Stockholm, Sweden.
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- Yang, Ying (author)
- Anhui Univ, Inst Phys Sci & Informat Technol, Hefei 230601, Anhui, Peoples R China.
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- Abbaszad Rafi, Abdolrahim (author)
- Mittuniversitetet,Institutionen för naturvetenskap
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- (creator_code:org_t)
- 2020-04-07
- 2020
- English.
- In: Angewandte Chemie International Edition. - : Wiley. - 1433-7851 .- 1521-3773. ; 59:26, s. 10391-10395
- Journal article (peer-reviewed)
Abstract
Subject headings
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- A silver-triggered heterogeneous Pd-catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one-pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride ions in the heterogeneous catalyst Pd-AmP-CNC, thereby generating highly active Pd-II, which results in high efficiency of the heterogeneous catalytic system.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- carbonylation
- heterogeneous catalysis
- palladium
- polycyclic compound
- silver
Publication and Content Type
- ref (subject category)
- art (subject category)
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