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  • Chiarinelli, Jacopo (author)

Electron and ion spectroscopy of the cyclo-alanine–alanine dipeptide

  • Article/chapterEnglish2022

Publisher, publication year, extent ...

  • 2022
  • Royal Society of Chemistry (RSC),2022
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:su-202636
  • https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-202636URI
  • https://doi.org/10.1039/d1cp05811hDOI

Supplementary language notes

  • Language:English
  • Summary in:English

Part of subdatabase

Classification

  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • The VUV photoionisation and photofragmentation of cyclo-alanine–alanine (cAA) has been studied in a joint experimental and theoretical work. The photoelectron spectrum and the photoelectron–photoion coincidence (PEPICO) measurements, which enable control of the energy being deposited, combined with quantum chemistry calculations, provide direct insight into the cAA molecular stability after photoionisation. The analysis of the ion-neutral coincidence experiments with the molecular dynamics simulations and the exploration of the potential energy surface allows a complete identification of the fragmentation pathways. It has been found that the fragmentation always starts with the ring opening through the C–C bond cleavage, followed by release of neutral CO or HNCO moieties.

Subject headings and genre

Added entries (persons, corporate bodies, meetings, titles ...)

  • Barreiro-Lage, Darío (author)
  • Bolognesi, Paola (author)
  • Richter, Robert (author)
  • Zettergren, HenningStockholms universitet,Fysikum(Swepub:su)henning (author)
  • Stockett, Mark H.Stockholms universitet,Fysikum(Swepub:su)mstoc (author)
  • Díaz-Tendero, Sergio (author)
  • Avaldi, Lorenzo (author)
  • Stockholms universitetFysikum (creator_code:org_t)

Related titles

  • In:Physical Chemistry, Chemical Physics - PCCP: Royal Society of Chemistry (RSC)24:10, s. 5855-58671463-90761463-9084

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