Ethyl 3,6-di-O-benzyl-2-deoxy-N-phthalimido-1-thio-β-D-glucopyranoside

Hamark, ChristofferStockholms universitet,Institutionen för organisk kemi (author)

Part: 12
In the title compound, C30H31NO6S, the plane of the N-phthalimido group is nearly orthogonal to the least-squares plane of the sugar ring (defined by atoms C2, C3, C5 and O5 using standard glucose nomenclature), making a dihedral angle of 72.8 (1)°. The thioethyl group has the exo-anomeric conformation. The hydroxy group forms an intermolecular hydrogen bond to the O atom in the sugar ring, generating [100] chains. There are four close - contacts with centroid-centroid distances less than 4.0 Å, all with dihedral angles between the interacting systems of only 8°, supporting energetically favourable stacking interactions

Landström, JensStockholms universitet,Institutionen för organisk kemi (author)
Eriksson, LarsStockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)lerik (author)
Widmalm, GöranStockholms universitet,Institutionen för organisk kemi(Swepub:su)gw (author)
Stockholms universitetInstitutionen för organisk kemi (creator_code:org_t)

By the author/editor: Hamark, Christof ...; Landström, Jens; Eriksson, Lars; Widmalm, Göran

About the subject

NATURAL SCIENCES: NATURAL SCIENCES; and Chemical Science ...; and Organic Chemistr ...

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