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Dissociative charge...
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Savee, John D.
(författare)
Dissociative charge exchange dynamics of HN2+ and DN2+
- Artikel/kapitelEngelska2009
Förlag, utgivningsår, omfång ...
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AIP Publishing,2009
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printrdacarrier
Nummerbeteckningar
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LIBRIS-ID:oai:DiVA.org:su-59677
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https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-59677URI
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https://doi.org/10.1063/1.3236803DOI
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:art swepub-publicationtype
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authorCount :4
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Translational spectroscopy coupled with coincidence detection techniques has been used to study the dissociation dynamics of ground state H/D+N-2 products resulting from charge exchange between keV beams of HN2+/DN2+ and cesium. Analysis of the product kinetic energy release suggests that dissociation of HN2 and DN2 proceeds from initial populations in the (2)A '', 2 (2)A ', and 3s Rydberg electronic states of the neutral molecule. Although all three excited electronic states must eventually couple to the 1 (2)A ' ground state of HN2/DN2, the resulting dissociation dynamics exhibit a significant dependence on the initial electronic state. Potential mechanisms are discussed in light of the observed product kinetic energy release distributions.
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Thomas, Richard D.Stockholms universitet,Fysikum(Swepub:su)rdt
(författare)
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Mann, Jennifer E.
(författare)
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Continetti, Robert E.
(författare)
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Stockholms universitetFysikum
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Journal of Chemical Physics: AIP Publishing131:13, s. 134301-0021-96061089-7690
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