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- Deng, YouqianStockholms universitet,Institutionen för organisk kemi (author)
Control of Selectivity in Palladium-Catalyzed Oxidative Carbocyclization/Borylation of Allenynes
- Article/chapterEnglish2013
Publisher, publication year, extent ...
- 2013-05-17
- Wiley,2013
- printrdacarrier
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- LIBRIS-ID:oai:DiVA.org:su-90111
- https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-90111URI
- https://doi.org/10.1002/anie.201301167DOI
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- Language:English
- Summary in:English
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- AuthorCount: 3;
- In control: A highly selective carbocyclization/borylation of allenynes with bis(pinacolato)diboron (B2pin2) under palladium catalysis and with p-benzoquinone (BQ) as the oxidant was developed. The use of either LiOAc⋅2 H2O with 1,2-dichloroethane (DCE) as the solvent or BF3⋅Et2O together with THF is crucial for the selective formation of borylated trienes and vinylallenes, respectively.
Subject headings and genre
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
- allenes
- boronates
- cyclization
- oxidation
- palladium
Added entries (persons, corporate bodies, meetings, titles ...)
- Teresa, BartholomeyzikStockholms universitet,Institutionen för organisk kemi(Swepub:su)teba2693 (author)
- Bäckvall, Jan-E.Stockholms universitet,Institutionen för organisk kemi(Swepub:su)backv (author)
- Stockholms universitetInstitutionen för organisk kemi (creator_code:org_t)
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- In:Angewandte Chemie International Edition: Wiley52:24, s. 6283-62871433-78511521-3773
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