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Capture of novel sp...
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Zhang, YingState Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, China
(author)
Capture of novel sp3 hybridized Z-BN by compressing boron nitride nanotubes with small diameter
- Article/chapterEnglish2022
Publisher, publication year, extent ...
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Elsevier,2022
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:umu-200450
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https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-200450URI
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https://doi.org/10.1016/j.diamond.2022.109431DOI
Supplementary language notes
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Language:English
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Summary in:English
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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Experimental synthesis of new sp3 hybridized carbon/boron nitride structures remains challenging despite that numerous sp3 structures have been proposed in theory. Here, we showed that compressed multi-walled boron nitride nanotubes (MWBNNTs) and boron nitride peapods (C60@BNNTs) with small diameters could transform into a new sp3 hybridized boron nitride allotrope (Z-BN). This strategy is considered from the topological transition point of view in boron nitride nanotubes upon compression. Due to the increased curvature in compressed small-diameter MWBNNTs, the uncommon 4- and 8-membered rings in Z-BN could be more favorably formed. And the irreversible tube collapse is proved to be a critical factor for the capture of the formed Z-BN, because of the competition between the resilience of tube before collapse and the stress limitation for the lattice stabilization of Z-BN upon decompression. In this case, Z-BN starts to form above 19.0 GPa, which is fully reversible below 45 GPa and finally becomes quenchable at 93.5 GPa. This collapse-induced capture of the high-pressure phase could also be extended to other tubular materials for quenching novel sp3 structures.
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Liu, ShuangState Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, China
(author)
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Yao, ZhenState Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, China
(author)
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Dong, JiajunState Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, China
(author)
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Liu, BoState Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, China
(author)
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Liu, RanState Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, China
(author)
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Du, MingrunCivil Aviation University of China, College of Science, Tianjin, China
(author)
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Wang, PengState Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, China
(author)
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Li, QuanjunState Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, China
(author)
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Wågberg, Thomas,1971-Umeå universitet,Institutionen för fysik(Swepub:umu)thwa0002
(author)
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Barzegar, Hamid RezaUmeå universitet,Institutionen för fysik(Swepub:umu)hare0009
(author)
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Zettl, AlexDepartment of Physics, University of California at Berkeley, Materials Sciences Division, Lawrence Berkeley National Laboratory, Kavli Energy Nano Science Institute at the University of California at Berkeley, Lawrence Berkeley National Laboratory, CA, Berkeley, United States
(author)
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Yao, MingguangState Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, China
(author)
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Liu, BingbingState Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, China
(author)
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State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun, ChinaCivil Aviation University of China, College of Science, Tianjin, China
(creator_code:org_t)
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In:Diamond and related materials: Elsevier1300925-96351879-0062
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Zhang, Ying
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Liu, Shuang
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Yao, Zhen
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Dong, Jiajun
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Liu, Bo
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Liu, Ran
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Du, Mingrun
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Wang, Peng
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