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Topochemical polyme...
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Soldatov, Alexander
(author)
Topochemical polymerization of C70 controlled by monomer crystal packing
- Article/chapterEnglish2001
Publisher, publication year, extent ...
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American Association for the Advanement of Science,2001
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:umu-22022
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https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-22022URI
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https://doi.org/10.1126/science.1061434DOI
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https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-12035URI
Supplementary language notes
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Language:English
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Summary in:English
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Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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Supplemental data available at http://www.sciencemag.org/cgi/content/full/293/5530/680/DC1
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Upprättat; 2001; 20061110 (ysko)
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Polymeric forms of C60 are now well known, but numerous attempts to obtain C70 in a polymeric state have yielded only dimers. Polymeric C70 has now been synthesized by treatment of hexagonally packed C70 single crystals under moderate hydrostatic pressure (2 gigapascals) at elevated temperature (300°C), which confirms predictions from our modeling of polymeric structures of C70. Single-crystal x-ray diffraction shows that the molecules are bridged into polymeric zigzag chains that extend along the c axis of the parent structure. Solid-state nuclear magnetic resonance and Raman data provide evidence for covalent chemical bonding between the C70 cages.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
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Roth, GeorgInstitut fur Kristallographie der Rheinisch-Westfahlische Technische Hochschule Aachen
(author)
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Dzyabchenko, AlexanderKarpov Institute of Physical Chemistry, Moscow
(author)
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Johnels, DanUmeå universitet,Kemiska institutionen,Umeå university(Swepub:umu)dajo0001
(author)
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Lebedkin, SergeiForschungszentrum Karlsruhe Technik und Umwelt
(author)
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Meingast, ChristophForschungszentrum Karlsruhe Technik und Umwelt
(author)
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Sundqvist, BertilUmeå universitet,Institutionen för fysik,Umeå university(Swepub:umu)besu0001
(author)
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Haluska, MiroInstitut fur Materialphysik, Universität Wien
(author)
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Kuzmany, HansInstitut fur Materialphysik, Universität Wien
(author)
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Institut fur Kristallographie der Rheinisch-Westfahlische Technische Hochschule AachenKarpov Institute of Physical Chemistry, Moscow
(creator_code:org_t)
Related titles
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In:Science: American Association for the Advanement of Science293:5530, s. 680-6830036-80751095-9203
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