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Search: AMNE:(NATURVETENSKAP Fysik Den kondenserade materiens fysik) > Topochemical polyme...

  • Soldatov, Alexander (author)

Topochemical polymerization of C70 controlled by monomer crystal packing

  • Article/chapterEnglish2001

Publisher, publication year, extent ...

  • American Association for the Advanement of Science,2001
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:umu-22022
  • https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-22022URI
  • https://doi.org/10.1126/science.1061434DOI
  • https://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-12035URI

Supplementary language notes

  • Language:English
  • Summary in:English

Part of subdatabase

Classification

  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • Supplemental data available at http://www.sciencemag.org/cgi/content/full/293/5530/680/DC1
  • Upprättat; 2001; 20061110 (ysko)
  • Polymeric forms of C60 are now well known, but numerous attempts to obtain C70 in a polymeric state have yielded only dimers. Polymeric C70 has now been synthesized by treatment of hexagonally packed C70 single crystals under moderate hydrostatic pressure (2 gigapascals) at elevated temperature (300°C), which confirms predictions from our modeling of polymeric structures of C70. Single-crystal x-ray diffraction shows that the molecules are bridged into polymeric zigzag chains that extend along the c axis of the parent structure. Solid-state nuclear magnetic resonance and Raman data provide evidence for covalent chemical bonding between the C70 cages.

Subject headings and genre

Added entries (persons, corporate bodies, meetings, titles ...)

  • Roth, GeorgInstitut fur Kristallographie der Rheinisch-Westfahlische Technische Hochschule Aachen (author)
  • Dzyabchenko, AlexanderKarpov Institute of Physical Chemistry, Moscow (author)
  • Johnels, DanUmeå universitet,Kemiska institutionen,Umeå university(Swepub:umu)dajo0001 (author)
  • Lebedkin, SergeiForschungszentrum Karlsruhe Technik und Umwelt (author)
  • Meingast, ChristophForschungszentrum Karlsruhe Technik und Umwelt (author)
  • Sundqvist, BertilUmeå universitet,Institutionen för fysik,Umeå university(Swepub:umu)besu0001 (author)
  • Haluska, MiroInstitut fur Materialphysik, Universität Wien (author)
  • Kuzmany, HansInstitut fur Materialphysik, Universität Wien (author)
  • Institut fur Kristallographie der Rheinisch-Westfahlische Technische Hochschule AachenKarpov Institute of Physical Chemistry, Moscow (creator_code:org_t)

Related titles

  • In:Science: American Association for the Advanement of Science293:5530, s. 680-6830036-80751095-9203

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