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- Andersson, OveUmeå universitet,Institutionen för fysik (author)
Thermal Conductivity and Heat Capacity of Dianin's Clathrates under Pressure
- Article/chapterEnglish2001
Publisher, publication year, extent ...
- 2001-12-08
- American Chemical Society (ACS),2001
- printrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:umu-225571
- https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-225571URI
- https://doi.org/10.1021/jp0126964DOI
Supplementary language notes
- Language:English
- Summary in:English
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Notes
- The thermal conductivities, λ, and heat capacities of polycrystalline Dianin’s compound and its CCl4 and ethanol clathrates have been investigated in the temperature range 40-300 K for pressures up to 1 GPa. All high-pressure results for λ show typical crystal-like behavior, whereas previous atmospheric pressure results for single crystals as well as recent results on polycrystalline samples show glasslike behavior. The change from glasslike to crystal-like dependence might be caused by a frequency shift of localized vibrations on pressurization, moving the localized vibrations outside the frequency range of the dominant heat carriers and reducing thermal resistance due to resonance scattering.
Subject headings and genre
- NATURVETENSKAP Fysik Den kondenserade materiens fysik hsv//swe
- NATURAL SCIENCES Physical Sciences Condensed Matter Physics hsv//eng
- Thermal conductivity
- high pressure
- Dianin's
- clathrate
- compound
- hydrate
- inclusion
- molecules
- adduct
- guests
Added entries (persons, corporate bodies, meetings, titles ...)
- Murashov, VladimirDepartment of Chemistry, Dalhousie UniVersity, Halifax, NoVa Scotia, Canada (author)
- White, Mary AnneDepartment of Chemistry, Dalhousie UniVersity, Halifax, NoVa Scotia, Canada (author)
- Umeå universitetInstitutionen för fysik (creator_code:org_t)
Related titles
- In:Journal of Physical Chemistry B: American Chemical Society (ACS)106:1, s. 192-1961520-61061520-5207
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