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Tetraethylammonium ...
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Berggren, GustavUppsala universitet,Institutionen för fotokemi och molekylärvetenskap
(author)
Tetraethylammonium [12,12-diethyl-2,2,9,9-tetramethyl-1,4,7,10-tetraza-5,6-benzotridecane-3 ,8,11,13-tetraone(4-)]oxidomanganate(V)
- Article/chapterEnglish2007
Publisher, publication year, extent ...
Numbers
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LIBRIS-ID:oai:DiVA.org:uu-108450
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-108450URI
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https://doi.org/10.1107/S1600536807047691DOI
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https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-21385URI
Supplementary language notes
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Language:English
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Summary in:English
Part of subdatabase
Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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Supplementary materials
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The Mn-V complex in the title compound, (C8H20N)[ Mn(C21H26N4O4)O], is interesting as it has been suggested that Mn-V oxospecies are intermediates both in epoxidation of alkenes and in water oxidation in PSII, i.e. photosystem II, the protein found in oxygenic photosynthetic organisms, which uses light to split water into O-2, protons and electrons. The Mn atom has a square-pyramidal coordination of four N atoms with an apical O atom. The four N atoms coordinating to Mn [Mn-N = 1.872 (2)-1.882 (2) angstrom] form a plane within 0.03 (3) angstrom from which the Mn ion is displaced by 0.582 (2) angstrom.
Subject headings and genre
Added entries (persons, corporate bodies, meetings, titles ...)
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Kaynak, F. B.
(author)
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Anderlund, Magnus F.Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap
(author)
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Eriksson, LarsStockholms universitet,Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi(Swepub:su)lerik
(author)
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Åkermark, BjörnStockholms universitet,Institutionen för organisk kemi(Swepub:su)baker
(author)
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Uppsala universitetInstitutionen för fotokemi och molekylärvetenskap
(creator_code:org_t)
Related titles
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In:Acta Crystallographica Section E63:11, s. M2672-M26731600-5368
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