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Direct synthesis of...
Direct synthesis of an heterometallic {(Mn3Cr4III)-Cr-II} wheel by decomposition of Reineckes salt
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Semenaka, Valentyna V. (author)
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Nesterova, Oksana V. (author)
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Kokozay, Volodymyr N. (author)
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Zybatyuk, Roman I. (author)
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Shishkin, Oleg V. (author)
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Boca, Roman (author)
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- Shevchenko, Denys V. (author)
- Uppsala universitet,Molekylär biomimetik
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- Huang, Ping (author)
- Uppsala universitet,Molekylär biomimetik
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- Styring, Stenbjörn (author)
- Uppsala universitet,Molekylär biomimetik
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(creator_code:org_t)
- Royal Society of Chemistry (RSC), 2010
- 2010
- English.
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In: Dalton Transactions. - : Royal Society of Chemistry (RSC). - 1477-9226 .- 1477-9234. ; 39:9, s. 2344-2349
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- A new heterometallic Mn/Cr molecular wheel complex has been synthesized using zerovalent manganese, Reineckes salt, ammonium thiocyanate and triethanolamine (H(3)tea) as starting materials. The compound [Mn3Cr4(NCS)(6)(Htea)(6)] (1) has been characterized in terms of its electrochemical, IR and EPR spectroscopic as well as its magnetic properties. The magnetic susceptibility and magnetization data were treated simultaneously during the optimization routine and resulted in J(Mn-Cr) = + 0.43 cm(-1), J(Cr-Cr) = -4.75 cm(-1), J(Mn-Mn) = +1.78 cm(-1), g(eff) = 1.878 with the ground state S = 15/2.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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