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  • Feifel, RaimundUppsala universitet,Fysik II (author)

Probing the valence character of O-1s -> Rydberg excited O-2 by participator Auger decay measurements and partial ion yield spectroscopy following x-ray absorption

  • Article/chapterEnglish2007

Publisher, publication year, extent ...

  • AIP Publishing,2007
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:uu-144709
  • https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-144709URI
  • https://doi.org/10.1063/1.2723745DOI
  • https://lup.lub.lu.se/record/662606URI

Supplementary language notes

  • Language:English
  • Summary in:English

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Classification

  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • The valence character of O 1s -> Rydberg excited O-2 is investigated by means of participator Auger decay spectroscopy, performed at selected photon energies across the K-shell resonance region, and by means of partial ion yield x-ray absorption spectroscopy. For several of the excitation energies studied, the authors find substantial sigma(*)((4)Sigma(-)(u),(2)Sigma(-)(u)) valence character being mixed with ns sigma and np sigma ((4)Sigma(-)(u),(2)Sigma(-)(u)) Rydberg states. An experimental indication of a coupling between the channels associated with quartet and doublet ion cores is considered and discussed. New spectroscopic constants are derived for the singly ionized X (2)Pi(g) state of O-2 based on the observation of at least 20 vibrational sublevels.

Subject headings and genre

Added entries (persons, corporate bodies, meetings, titles ...)

  • Tanaka, T. (author)
  • Kitajima, M. (author)
  • Tanaka, H. (author)
  • De Fanis, A. (author)
  • Sankari, R. (author)
  • Karlsson, L.Uppsala universitet,Fysik II (author)
  • Ristinmaa Sörensen, StaceyLund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)slju-sri (author)
  • Piancastelli, Maria NovellaUppsala universitet,Fysik V (author)
  • Prümper, G. (author)
  • Hergenhahn, U. (author)
  • Ueda, K. (author)
  • Uppsala universitetFysik II (creator_code:org_t)

Related titles

  • In:Journal of Chemical Physics: AIP Publishing126:17, s. 174304-0021-96061089-7690

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