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- Savitski, Mikhail M.Uppsala universitet,MMS, medicinsk masspektrometri (author)
Backbone carbonyl group basicities are related to gas-phase fragmentation of peptides and protein folding
- Article/chapterEnglish2007
Publisher, publication year, extent ...
- Wiley,2007
- printrdacarrier
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- LIBRIS-ID:oai:DiVA.org:uu-145840
- https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-145840URI
- https://doi.org/10.1002/anie.200603881DOI
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- Language:English
- Summary in:English
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- A strong correlation is found between the propensity of individual amino acids to induce peptide-bond cleavage in the gas phase (PAA-XX) and their structure-forming propensity (PS, red) and H-bond-accepting propensity (PH, blue). Thus, the same fundamental parameter, carbonyl group basicity, governs the formation of secondary protein structures in solution and directs fragmentation in the gas phase. (Graph Presented).
Subject headings and genre
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
- hydrogen bonds
- mass spectrometry
- peptide fragmentation
- protein structures
- proteomics
- Chemistry
- Kemi
Added entries (persons, corporate bodies, meetings, titles ...)
- Kjeldsen, FrankUppsala universitet,MMS, medicinsk masspektrometri (author)
- Nielsen, Michael L.Uppsala universitet,MMS, medicinsk masspektrometri (author)
- Garbuzynskiy, Sergiy O. (author)
- Galzitskaya, Oxana V. (author)
- Surin, Alexey K. (author)
- Zubarev, Roman A.Uppsala universitet,MMS, medicinsk masspektrometri (author)
- Uppsala universitetMMS, medicinsk masspektrometri (creator_code:org_t)
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- In:Angewandte Chemie International Edition: Wiley46:9, s. 1481-14841433-78511521-3773
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