L773:1364 548X OR L773:1359 7345
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Pentacoordinate iron complexes as functional models of the distal iron in [FeFe] hydrogenases
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- Beyler, Maryline (author)
- Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap
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- Ezzaher, Salah (author)
- Uppsala universitet,Institutionen för fotokemi och molekylärvetenskap
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- Karnahl, Michael (author)
- Uppsala universitet,Molekylär biomimetik
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- Royal Society of Chemistry (RSC), 2011
- 2011
- English.
- In: Chemical Communications. - : Royal Society of Chemistry (RSC). - 1359-7345 .- 1364-548X. ; 47:42, s. 11662-11664
- Journal article (peer-reviewed)
Abstract
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- Mononuclear pentacoordinate iron complexes with a free coordination site were prepared as mimics of the distal Fe (Fe(d)) in the active site of [FeFe] hydrogenases. The complexes catalyze the electrochemical reduction of protons at mild overpotential.
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