Laboratory-frame electron angular distributions : Probing the chemical environment through intramolecular electron scattering

• Carbon 1s photoelectron asymmetry parameters beta for the chlorinated and the methyl carbon atom of CH3CH2Cl, CH3CHCl2, and CH3CCl3 have been measured using synchrotron radiation in the 340-600 eV energy range. We provide experimental evidence that the intramolecular scattering strongly affects beta values, even far from the ionization threshold. The results are in agreement with B-spline density functional theory calculations, making it possible to single out the behavior of the various continuum partial waves. We conclude that the intramolecular scattering makes electron angular distributions sensitive to the chemical environment, even in isolated gas phase molecules.

Subject headings

NATURVETENSKAP  -- Fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences (hsv//eng)

Keyword

Fysik med inriktning mot atom- molekyl- och kondenserande materiens fysik

Physics with spec. in Atomic, Molecular and Condensed Matter Physics

Publication and Content Type

ref (subject category)

art (subject category)