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- Hermansson, KerstiUppsala universitet,Kemiska institutionen (author)
Hydrogen bond studies. CXX. An X-ray determination of the crystal structure of LiNO 3.3H 2O
- Article/chapterEnglish1977
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- 1977
- printrdacarrier
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- LIBRIS-ID:oai:DiVA.org:uu-228737
- https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-228737URI
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- Language:English
- Summary in:English
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Notes
- For pt.CXIX see Z. Naturforsch. a, vol.32, p.134 (1977). The crystal structure of lithium nitrate trihydrate, LiNO 3.3H 2O, has been determined by X-ray diffraction at 295K. The crystal is orthorhombic, space group Cmcm, a=6.8018 (4), b=12.7132 (9), c=5.9990 (4) Aring, V=518.75 Aring 3, Z=4. The nitrate ions, Li + ions and one of the two crystallographically non-equivalent water molecules lie in a mirror plane and are bonded to atoms in adjacent planes through the second water molecule. The Li + ion is octahedrally surrounded by six O atoms, four belonging to water molecules and two to nitrate ions. The two non-equivalent water molecules are present in the structure in distinctly different bonding situations. One is bonded to two Li + ions and is the donor of two hydrogen bonds. The other is involved in six hydrogen bonds: the O atom accepts two hydrogen bonds, and both protons are involved in bifurcated hydrogen bonds.
Subject headings and genre
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
- Experimental/ hydrogen bonds
- lithium compounds/ X-ray determination
- crystal structure
- LiNO 3.3H 2O
- H-bond/ A6160 Crystal structure of specific inorganic compounds
Added entries (persons, corporate bodies, meetings, titles ...)
- Thomas, J. O. (author)
- Olovsson, I. (author)
- Uppsala universitetKemiska institutionen (creator_code:org_t)
Related titles
- In:Acta Crystallogr. B, Struct. Crystallogr. Cryst. Chem. (Denmark)B33, s. 2857-28610567-7408
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