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Transient mid-IR study of electron dynamics in TiO2 conduction band.

Sá, Jacinto (author)
Friedli, Peter (author)
Geiger, Richard (author)
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Lerch, Philippe (author)
Rittmann-Frank, Mercedes H (author)
Milne, Christopher J (author)
Szlachetko, Jakub (author)
Santomauro, Fabio G (author)
van Bokhoven, Jeroen A (author)
Chergui, Majed (author)
Rossi, Michel J (author)
Sigg, Hans (author)
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Royal Society of Chemistry (RSC), 2013
2013
English.
In: The Analyst. - : Royal Society of Chemistry (RSC). - 0003-2654 .- 1364-5528. ; 138:7, s. 1966-70
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • The dynamics of TiO2 conduction band electrons were followed with a novel broadband synchrotron-based transient mid-IR spectroscopy setup. The lifetime of conduction band electrons was found to be dependent on the injection method used. Direct band gap excitation results in a lifetime of 2.5 ns, whereas indirect excitation at 532 nm via Ru-N719 dye followed by injection from the dye into TiO2 results in a lifetime of 5.9 ns.

Subject headings

NATURVETENSKAP  -- Kemi -- Fysikalisk kemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Physical Chemistry (hsv//eng)

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