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- Jabre-Truffert, SUppsala universitet,Kemiska institutionen (author)
Evidence for the intermediacy of (eta(3)-allyl)palladium complexes in the palladium-catalyzed acryloxylation of cycloalkenes: Unexpected oxidation of 1,5-cyclooctadiene
- Article/chapterEnglish2000
Publisher, publication year, extent ...
- WILEY-V C H VERLAG GMBH,2000
- printrdacarrier
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- LIBRIS-ID:oai:DiVA.org:uu-37578
- https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-37578URI
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- Language:English
- Summary in:English
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- Addresses: Waegell B, Fac Sci St Jerome, CNRS, Lab Stereochim, Ave Escadrille Normandie Niemen Case 532, F-13397 Marseille 20, France. Fac Sci St Jerome, CNRS, Lab Stereochim, F-13397 Marseille 20, France. Univ Uppsala, Dept Organ Chem, S-75121 Uppsala, S
- Palladium-catalyzed acryloxylation of several cycloalkenes in the presence of the Pd(OAc)(2)/p-benzoquinone/MnO2 catalytic system is reported. This oxidation reaction yields allylic acrylates as the sole products through the intermediacy of an eta(3)-ally
Subject headings and genre
- homogeneous catalysis; palladium; acetoxylation; acryloxylation; 1;2-addition reactions; 1;5-cyclooctadiene; cyclooct-4-enone; METHYLENE-GAMMA-BUTYROLACTONES; ALLYLIC ACETOXYLATION; ALKENES
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- Delmas, AM (author)
- Grennberg, H (author)
- Akermark, B (author)
- Waegell, B (author)
- Uppsala universitetKemiska institutionen (creator_code:org_t)
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- In:EUROPEAN JOURNAL OF ORGANIC CHEMISTRY: WILEY-V C H VERLAG GMBH:1, s. 219-2241434-193X
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