Intramolecular homolytic substitution at selenium: Synthesis of novel selenium-containing vitamin E analogues

• Treatment of 1-(benzylselenenyl)-5-butyl-5-nonanoI (10) with oxalyl chloride followed by the sodium salt of N-hydroxypyridine-2-thione afforded the corresponding pyridine-2-thione-N-oxycarbonyI (PTOC) oxalate ester which was not isolated but immediately h

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PENTOSE STARTING MATERIALS; THIOL PEROXIDASE-ACTIVITY; FREE-RADICAL SYNTHESIS; LIPID-PEROXIDATION; ORGANOTELLURIUM COMPOUNDS; ANTIOXIDANT ACTIVITY; DIARYL TELLURIDES; TERTIARY ALCOHOLS; CONTAINING HETEROCYCLES; S(RN)1/S(H)I REACTIONS

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