Preparation, structure, and properties of a new giant manganese oxo-alkoxide wheel, [Mn19O12(OC2H4OCH3)(14)(HOC2H4OCH3)(10)]center dot HOC2H4OCH3

• Alkoxides are of great interest as precursors for sol-gel processing of advanced ceramic materials, but there is very little general knowledge about the low-valent 3d-element alkoxides. The novel oxo-alkoxide, [Mn19O12(moe)(14)- (moeH)(10)] . MOEH (MOE =

Ämnesord

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

Nyckelord

alkoxides; IR spectroscopy; manganese; structural elucidation; UV/Vis spectroscopy; RAY CRYSTAL-STRUCTURES; CA-MN-O; NONVOLATILE MEMORY DEVICES; BOND-VALENCE PARAMETERS; MAGNETIC-PROPERTIES; MOLECULAR-STRUCTURE; YMNO3 FILM; THIN-FILMS; MAGNETORESISTANCE

Inorganic chemistry

Oorganisk kemi

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