Efficient visible light-driven water oxidation catalysed by an iron(IV) clathrochelate complex

• A water-stable FeIV clathrochelate complex catalyzes fast and homogeneous photochemical oxidation of water to dioxygen with a turnover frequency of 2.27 s−1 and a maximum turnover number of 365. An FeV intermediate generated under catalytic conditions is trapped and characterised using EPR and Mössbauer spectroscopy.

Ämnesord

NATURVETENSKAP  -- Kemi -- Fysikalisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Physical Chemistry (hsv//eng)

Nyckelord

Artificial photosynthesis

water oxidation

iron catalyst

photochemical water oxidation

electrochemical water oxidation

Chemistry with specialization in Physical Chemistry

Kemi med inriktning mot fysikalisk kemi

Publikations- och innehållstyp

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