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How microalloying o...
How microalloying of the Al target can improve process and film characteristics of sputtered alumina
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- Kohlhauser, B. (författare)
- TU Wien, Inst Mat Sci & Technol, A-1060 Vienna, Austria.;AC2T Res GmbH, A-2700 Wiener Neustack, Austria.
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- Riedl, H. (författare)
- TU Wien, Inst Mat Sci & Technol, A-1060 Vienna, Austria.
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- Koller, C. M. (författare)
- TU Wien, Inst Mat Sci & Technol, A-1060 Vienna, Austria.
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- Paneta, Valentina (författare)
- Uppsala universitet,Tillämpad kärnfysik
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- Kolozsvari, S. (författare)
- Plansee Composite Mat GmbH, D-86983 Lechbruck, Germany.
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- Mayrhofer, P. H. (författare)
- TU Wien, Inst Mat Sci & Technol, A-1060 Vienna, Austria.
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TU Wien, Inst Mat Sci & Technol, A-1060 Vienna, Austria;AC2T Res GmbH, A-2700 Wiener Neustack, Austria. TU Wien, Inst Mat Sci & Technol, A-1060 Vienna, Austria. (creator_code:org_t)
- ELSEVIER SCIENCE SA, 2020
- 2020
- Engelska.
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Ingår i: Surface & Coatings Technology. - : ELSEVIER SCIENCE SA. - 0257-8972 .- 1879-3347. ; 393
- Relaterad länk:
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https://doi.org/10.1...
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https://uu.diva-port... (primary) (Raw object)
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https://doi.org/10.1...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The outstanding thermo-mechanical and chemical stability of Al2O3 thin films attracts particular attention in academia and industry. Here we show that alloying of the powder metallurgically prepared Al targets with 2 as well as 5 at.% of Cr, Mo, or W significantly improves the process stability (e.g., reducing arcing events) for Al2O3, allowing their reactive magnetron sputtering in DC mode (substrate temperature was always 360 degrees C). Contrary to these microalloying elements, Nb did not change or improve the process characteristics of the Al target due to the relatively coarse Nb particles (< 125 mu m). Particularly the small (< 10 mu m) and fine-dispersed W particles are very effective in stopping the collision cascades to concentrate them to the near subsurface target-regions. This leads to a shift of the target-poisoning onset from O-2/(Ar + O-2) flow-rate-ratios of about 32 to 52%, specifically when adding 5 at.% to the Al target. Thereby also improved deposition rates are possible. However, detailed X-ray diffraction (XRD) and transmission electron microscopy studies show that only thin films developed from the 2 at.% W alloyed Al target have a nanocrystalline gamma-Al2O3-based structure comparable to those prepared from Al or Cr alloyed Al targets. The films are with 28.3 GPa instead of 26.8 GPa slightly harder when sputtered from Al0.98W0.02 instead of Al targets. Higher W contents (and also Nb) in the target lead to the formation of Al2O3-based films with considerably lower crystalline phase fractions and hardness (similar to 13 GPa). Hardest films, with 30.0 and 29.6 GPa, are obtained when using Al0.98Cr0.02 and Al0.98Cr0.05 targets, respectively. The formation of volatile Mo-oxides during film growth interferes the structure development, leading to rather soft films with 8.0 GPa especially when using the higher Mo alloyed Al0.98Cr0.05 target. Based on our results we can conclude that microalloying the Al targets with small and fine-dispersed Cr or W particles not just improves process stability and deposition rate during reactive sputtering of Al2O3, but also their mechanical thin film properties.
Ämnesord
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Bearbetnings-, yt- och fogningsteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Manufacturing, Surface and Joining Technology (hsv//eng)
Nyckelord
- Micro-alloying
- Al2O3
- Target hysteresis
- Target poisoning
- Transition metals
- Mechanical properties
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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