Manifestation of the paramagnetic splitting of physisorbed O-2 in core and valence spectroscopies

• We have investigated the core excited sigma* resonance region in 1 monolayer of O-2, physisorbed on several substrates. Comparisons with the paramagnetic splitting obtained in X-ray photoelectron spectroscopy (XPS) and in ultraviolet photoelectron spectro

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ab initio quantum chemical methods and calculations; carbon; near edge extended X-ray absorption fine structure (NEXAFS); oxygen; platinum; silver; single crystal surfaces; X-ray photoelectron spectroscopy; PHOTOELECTRON-SPECTRA; O2; MOLECULES; STATES; OR

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