The crystal structures of PdNi2P and Pd8Ni31P16

• Two new ternary intermediate phases in the Pd-Ni-P system have been synthesized and the crystal structures have been determined by single-crystal X-ray diffraction. PdNi2P crystallizes in the MgCuAl2-type structure with the unit cell parameters a = 3.4708(3) Å, b = 8.4437(8) Å, c = 6.6083(5) Å, Z = 4, space group Cmcm. Pd8Ni31P16 is tetragonal with the unit cell parameters crystallographic non-equivalent positions This Hnes nnt crystallographic non-equivalent positions. This does not correspond to any previously reported structure.

Subject headings

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

Keyword

Transition metal phosphide

Crystal structure

X-ray diffraction

Inorganic chemistry

Oorganisk kemi

Publication and Content Type

ref (subject category)

art (subject category)