Sökning: WFRF:(Mahmood Asif) >
3D porous sulfur-gr...
3D porous sulfur-graphdiyne with splendid electrocatalytic and energy storage application
-
- Muhammad, Imran (författare)
- Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China.;Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalyt Chem, Shenzhen 518055, Guangdong, Peoples R China.
-
- Ahmed, Shehzad (författare)
- Shenzhen Univ, Coll Phys & Optoelect Engn, Shenzhen 518060, Guangdong, Peoples R China.
-
- Cao, Hao (författare)
- Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China.;Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalyt Chem, Shenzhen 518055, Guangdong, Peoples R China.
-
visa fler...
-
- Yao, Zhen (författare)
- Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China.;Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalyt Chem, Shenzhen 518055, Guangdong, Peoples R China.
-
- Khan, Danish (författare)
- Shenzhen Technol Univ, Coll New Mat & New Energies, Shenzhen 518118, Guangdong, Peoples R China.
-
- Mahmood, Asif (författare)
- Univ Technol Sydney, Ctr Clean Energy Technol, Sch Math & Phys Sci, Sydney, NSW 2007, Australia.
-
- Hussain, Tanveer (författare)
- Univ New England, Sch Sci & Technol, Armidale, NSW 2351, Australia.
-
- Xiong, Xiao-Gen (författare)
- Sun Yat sen Univ, Sino French Inst Nucl Engn & Technol, Zhuhai 519082, Peoples R China.
-
- Ahuja, Rajeev, 1965- (författare)
- Uppsala universitet,Materialteori,Indian Inst Technol Ropar, Dept Phys, Rupnagar 140001, Punjab, India
-
- Wang, Yang-Gang (författare)
- Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China.;Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalyt Chem, Shenzhen 518055, Guangdong, Peoples R China.
-
visa färre...
-
Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Guangdong, Peoples R China;Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalyt Chem, Shenzhen 518055, Guangdong, Peoples R China. Shenzhen Univ, Coll Phys & Optoelect Engn, Shenzhen 518060, Guangdong, Peoples R China. (creator_code:org_t)
- Elsevier, 2023
- 2023
- Engelska.
-
Ingår i: Materials Today Chemistry. - : Elsevier. - 2468-5194. ; 34
- Relaterad länk:
-
https://urn.kb.se/re...
-
visa fler...
-
https://doi.org/10.1...
-
visa färre...
Abstract
Ämnesord
Stäng
- The blooming emergence of graphdiyne featuring embellished sp-hybridized carbons has been highly alluring for electrocatalysis and ion storage. Here, a porous 3D material sulfur-graphdiyne (3D-SGDY) is theoretically designed comprising butadiyne chains and sulfur as a heteroatom, owing a stable cubic skeleton and an atypical tuneable indirect bandgap. Compared to sp2-bonded carbon materials, the existence of sp-bonded carbon in 3D-SGDY tuned the direction of organic reactions leading to a single carbon product with numerous storage sites for the metal ions. Anchoring a single Cu atom in 3D-SGDY, we realize the unique Cu–C (3D-SGDY) chemical bonds exhibiting unconventional selectivity for CO2 reduction. The Cu–C bond in 3D-SGDY predominantly forms the *OCHO intermediates in lieu of *COOH and provides an active charge deportation channel during the reduction process of CO2 into CH4 product. Additionally, the porous structure reveals its astounding potential as an anode material by facilitating rapid transportation with a very low diffusion barrier of 0.06 eV and an ultrahigh capacity of 1826.4 mAhg−1 for Ca-ions. This work not only provides the 3D prototype of GDY but also administers the atomic level selectivity for CO2RR and high-performance Ca-ion batteries.
Ämnesord
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Annan materialteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Other Materials Engineering (hsv//eng)
Nyckelord
- 3D sulfur graphdiyne
- Tuneable bandgap
- Selective CO 2 reduction
- Metal-ion batteries
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
Hitta via bibliotek
Till lärosätets databas
- Av författaren/redakt...
-
Muhammad, Imran
-
Ahmed, Shehzad
-
Cao, Hao
-
Yao, Zhen
-
Khan, Danish
-
Mahmood, Asif
-
visa fler...
-
Hussain, Tanveer
-
Xiong, Xiao-Gen
-
Ahuja, Rajeev, 1 ...
-
Wang, Yang-Gang
-
visa färre...
- Om ämnet
-
- NATURVETENSKAP
-
NATURVETENSKAP
-
och Kemi
-
och Materialkemi
-
- TEKNIK OCH TEKNOLOGIER
-
TEKNIK OCH TEKNO ...
-
och Materialteknik
-
och Annan materialte ...
- Artiklar i publikationen
-
Materials Today ...
- Av lärosätet
-
Uppsala universitet