Vibrational fine structure in core level photoelectron lines of adsorbed molecules: System dependent effects

• System dependent effects in resolving vibrational fine structure in the corn-level lines of adsorbates are discussed. The example is carbon monoxide on transition metals. The importance of dynamic metallic screening is exemplified and the role of shake-up

Nyckelord

photoemission; vibrational fine structure; adsorption; CO; Ni(100); Cu(100); shake-up; screening; equivalent cores; NO; magnetism; exchange splitting; PHOTOEMISSION SPECTRA; PHOTOIONIZATION; CO/NI(100); EXCITATION; CARBON; STATES; SHAPE; AUGER; C-1S

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