Transition-state structures for describing the enzyme-catalyzed mechanisms of rubisco

• The carboxylation and oxygenation processes of a model substrate, 3,4-dihydroxy-2-pentanone, have been theoreticaly characterized as a set of steps? mimicking the corresponding reactions of D-ribulose-1,5-bisphosphate catalyzed by rubisco. A theoretical c

Keyword

rubisco mechanism; transition-state structures; ab initio calculations; RIBULOSE 1;5-BISPHOSPHATE CARBOXYLASE; SITE-DIRECTED MUTAGENESIS; RIBULOSEBISPHOSPHATE CARBOXYLASE; BISPHOSPHATE CARBOXYLASE; RIBULOSE-1;5-BISPHOSPHATE CARBOXYLASE; ACTIVE-SITE; SLOW

Publication and Content Type

vet (subject category)

art (subject category)