Solvent Dependence of Enantioselectivity for a Base Catalyzed 1,3-Hydron Transfer Reaction : A Kinetic Isotope Effect and NMR Spectroscopic Study.

• The base-catalyzed rearrangement of 1-methylindene (1) to 3-methylindene (2) has been studied. The reaction proceeds with substrate enantioselectivity (kinetic resolution) when chiral tertiary amines are used as catalysts. When dihydroquinidine (DHQD) (3

Ämnesord

NATURVETENSKAP  -- Kemi -- Organisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Organic Chemistry (hsv//eng)

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Chemistry with specialization in Organic Chemistry

Kemi med inriktning mot organisk kemi

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