Resonant x-ray scattering beyond the Born-Oppenheimer approximation: Symmetry breaking in the oxygen resonant x-ray emission spectrum of carbon dioxide

• Although resonant x-ray scattering of molecules fulfills strict electronic symmetry selection rules, as now firmly proven by. spectra of diatomic molecules, the accumulated body of data for polyatomic molecules indicates that an apparent breaking of these

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VIBRATIONAL STRUCTURE; ELECTRONIC-SPECTRA; CORE; FLUORESCENCE; EXCITATION; STATES; LOCALIZATION; SPECTROSCOPY; DYNAMICS; ETHYLENE

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