Direct XRD observation of oxidation-state changes on Li-ion insertion into transition-metal oxide hosts

• It is demonstrated here that the electron redistribution occurring as lithium becomes incorporated into or extracted from a crystalline transition-metal oxide (TMO) host can be studied experimentally by single-crystal X-ray diffraction (XRD) for the case

Subject headings

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

Keyword

vanadium oxide; cathode material; lithium insertion mechanism; in situ X-ray diffraction; deformation electron density refinement; SINGLE-PHASE V6O13; VANADIUM-OXIDE; LITHIUM CELLS; BATTERY

Inorganic chemistry

Oorganisk kemi

Publication and Content Type

vet (subject category)

art (subject category)