1,3-hydron transfer in some 5- or 7-substituted 1-methylindenes. Reaction rates and kinetic isotope effects

• Rate constants and primary deuterium kinetic isotope effects (KIEs) have been determined for the base-catalysed 1,3-hydrotropic rearrangements of 1-methyl-5-nitroindene (12), 1-methyl-7-nitroindene (13), 5-methoxy-1-methylindene (14) and 5-fluoro-1-methy

Ämnesord

NATURVETENSKAP  -- Kemi -- Organisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Organic Chemistry (hsv//eng)

Nyckelord

CATALYZED 1;3-PROTON TRANSFER; SOLVENT DEPENDENCE; REARRANGEMENT; ELIMINATION

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