New expedient route to both enantiomers of nonproteinogenic alpha-amino acid derivatives from the unsaturated 2-aza-bicyclo moiety

• The influence of the reaction conditions on the catalytic hydrogenation of 2-aza-bicyclo hept-5-ene and oct-5-ene derivatives has been investigated. We found it possible to fully control the extent of allylic vs benzylic C-N hydrogenolysis by simple vari

Nyckelord

ENANTIOSELECTIVE ADDITION; ASYMMETRIC-SYNTHESIS; STEREOSELECTIVE SYNTHESIS; CHIRAL CATALYSTS; LIGANDS; DIETHYLZINC; OLEFINS; 2-AZANORBORNYLMETHANOLS; CYCLOPROPANATION; ARYLGLYCINES

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