Chiral N,N '- and N,O-bidentate anionic ligands. Preparation, metal complexation, and evaluation in the asymmetric aziridination of olefins

• The chiral ligands 1-phenyl-2-[(4S)-phenyl-4,5-dihydrooxazol-2-yl]propen-2-ol (1a) and [1-phenyl-2-((4S)-phenyl-4,5-dihydrooxazol-2-yl)vinyl]-p-tolylamine (2a) were prepared, together with some structural analogues (1b-e, 2b) in two steps from optically

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CRYSTAL-STRUCTURES; COPPER-COMPLEXES; CATALYSTS; ACIDS; CYCLOPROPANATION; THIAZOLINES; SEMICORRINS; OXAZOLINES; ENAMINES; ALKENES

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