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Absolute core-level...
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Tchaplyguine, MaximLund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory
(author)
Absolute core-level binding energy shifts between atom and solid: The Born-Haber cycle revisited for free nanoscale metal clusters
- Article/chapterEnglish2008
Publisher, publication year, extent ...
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Elsevier BV,2008
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printrdacarrier
Numbers
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LIBRIS-ID:oai:DiVA.org:uu-97640
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-97640URI
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https://doi.org/10.1016/j.elspec.2008.05.001DOI
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https://lup.lub.lu.se/record/965632URI
Supplementary language notes
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Language:English
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Summary in:English
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Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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Core-level binding energy shifts between the free atom and corresponding large clusters, the latter closely approximating the infinite solid, have been experimentally derived for several elemental metals. The cluster core-level binding energies in question have been determined relative to the vacuum level using synchrotron-based photoelectron spectroscopy. As expected, the experimental shift values show reasonable agreement with those calculated using the thermochemical Born–Haber cycle approach. The largest uncertainty factors defining the discrepancies between the experiment and the model, such as the difference in the multiplet structure of free atoms and the solid, the in some cases indirectly established cluster work functions, and the metal solvation energy, are discussed.
Subject headings and genre
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Peredkov, S.Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)maxl-spe
(author)
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Rosso, AldanaUppsala University,Uppsala universitet,Yt- och gränsskiktsvetenskap(Swepub:lu)maxl-aro
(author)
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Bradeanu, IoanaUppsala University,Uppsala universitet,Yt- och gränsskiktsvetenskap
(author)
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Öhrwall, GunnarUppsala University(Swepub:lu)maxl-goh
(author)
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Legendre, SébastienUppsala University,Uppsala universitet,Yt- och gränsskiktsvetenskap(Swepub:lu)maxl-sbl
(author)
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Svensson, S.Uppsala universitet,Uppsala University,Lund University,Lunds universitet,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,Yt- och gränsskiktsvetenskap(Swepub:uu)svansven
(author)
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Mårtensson, NilsUppsala University,Lund University,Lunds universitet,Uppsala universitet,Yt- och gränsskiktsvetenskap,MAX IV-laboratoriet,MAX IV Laboratory(Swepub:lu)maxl-nma
(author)
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Svensson, SvanteUppsala universitet,Yt- och gränsskiktsvetenskap(Swepub:uu)svansven
(author)
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Björneholm, OlleLund University,Lunds universitet,Uppsala universitet,Yt- och gränsskiktsvetenskap,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Department of Physics,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)maxl-obn
(author)
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Ristinmaa Sörensen, StaceyLund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)slju-sri
(author)
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Lunds universitetMAX IV-laboratoriet
(creator_code:org_t)
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In:Journal of Electron Spectroscopy and Related Phenomena: Elsevier BV166, s. 38-440368-20481873-2526
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Tchaplyguine, Ma ...
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Peredkov, S.
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Rosso, Aldana
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Bradeanu, Ioana
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Öhrwall, Gunnar
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Legendre, Sébast ...
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Svensson, S.
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Mårtensson, Nils
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Svensson, Svante
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Björneholm, Olle
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Ristinmaa Sörens ...
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