Sökning: WFRF:(Andersson Patrik U 1970) >
Proton mobility in ...
Proton mobility in water clusters
-
- Ryding, Mauritz Johan, 1981 (författare)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
-
- Andersson, Patrik U, 1970 (författare)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
-
Zatula, A. S. (författare)
-
visa fler...
-
Uggerud, E. (författare)
-
visa färre...
-
(creator_code:org_t)
- 2012-04-01
- 2012
- Engelska.
-
Ingår i: European Journal of Mass Spectrometry. - : SAGE Publications. - 1469-0667 .- 1751-6838. ; 18:2, s. 215-222
- Relaterad länk:
-
https://gup.ub.gu.se...
-
visa fler...
-
https://doi.org/10.1...
-
visa färre...
Abstract
Ämnesord
Stäng
- Proton mobility in water occurs quickly according to the so-called Grotthuss mechanism. This process and its elementary reaction steps can be studied in great detail by applying suitable mass spectrometric methods to ionic water clusters. Careful choice of suitable core ions in combination with analysis of cluster size trends in hydrogen/deuterium isotope exchange rates allows for detailed insights into fascinating dynamic systems. Analysis of the experiments has been promoted by extensive and systematic quantum chemical model calculations. Detailed low-energy mechanistic pathways for efficient water rearrangement and proton transfer steps, in particular cases along short preformed "wires" of hydrogen bonds, have been identified in consistency with experimental findings.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- mass spectrometry
- atmospheric chemistry
- heavy water
- proton transfer
- ion conductivity
- pyridine
- tropospheric ions
- mass-spectrometry
- continental air
- exchange
- pyridine
- identification
- chemistry
- d2o
- dissociation
- solvation
- nner dj
- 1991
- journal of geophysical research-atmospheres
- v96
- p1023
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
Hitta via bibliotek
Till lärosätets databas