id:"swepub:oai:gup.ub.gu.se/170412"
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- Ekebergh, Andreas,1984Chalmers tekniska högskola,Chalmers University of Technology (author)
Total Synthesis of Nostodione A, a Cyanobacterial Metabolite
- Article/chapterEnglish2012
Publisher, publication year, extent ...
- 2012-12-10
- American Chemical Society (ACS),2012
- electronicrdacarrier
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- LIBRIS-ID:oai:gup.ub.gu.se/170412
- https://gup.ub.gu.se/publication/170412URI
- https://doi.org/10.1021/ol303036jDOI
- https://research.chalmers.se/publication/170412URI
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- Language:English
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Notes
- The first total synthesis of the mitotic spindle poison nostodione A is described. The inherent oxidative sensitivity of indoles is utilized for a late introduction of a second carbonyl to the cyclopent[b]indole-2-one system. The tricyclic system is prepared from indole-3-acetic acid and O-silylated 4-ethynylphenol, using a stereoselective intramolecular reductive Heck cyclization as the key transformation.
Subject headings and genre
- NATURVETENSKAP Kemi hsv//swe
- NATURAL SCIENCES Chemical Sciences hsv//eng
Added entries (persons, corporate bodies, meetings, titles ...)
- Börje, Anna,1961Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology,University of Gothenburg(Swepub:gu)xboann (author)
- Mårtensson, Jerker,1965Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)jerker (author)
- Chalmers tekniska högskolaInstitutionen för kemi och molekylärbiologi (creator_code:org_t)
Related titles
- In:Organic Letters: American Chemical Society (ACS)14:24, s. 6274-62771523-70601523-7052
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