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Influence of Humidi...
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Emanuelsson, Eva U.Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
(author)
Influence of Humidity, Temperature, and Radicals on the Formation and Thermal Properties of Secondary Organic Aerosol (SOA) from Ozonolysis of β-Pinene
- Article/chapterEnglish2013
Publisher, publication year, extent ...
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2013-09-24
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American Chemical Society (ACS),2013
Numbers
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LIBRIS-ID:oai:gup.ub.gu.se/187998
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https://gup.ub.gu.se/publication/187998URI
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https://doi.org/10.1021/jp4010218DOI
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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The influence of water and radicals on SOAs produced by β-pinene ozonolysis was investigated at 298 and 288 K using a laminar flow reactor. A volatility tandem differential mobility analyzer (VTDMA) was used to measure the evaporation of the SOA, enabling the parametrization of its volatility properties. The parameters extracted included the temperature at which 50% of the aerosol had evaporated (TVFR0.5) and the slope factor (SVFR). An increase in SVFR indicates a broader distribution of vapor pressures for the aerosol constituents. Reducing the reaction temperature increased SVFR and decreased TVFR0.5 under humid conditions but had less effect on TVFR0.5 under dry conditions. In general, higher water concentrations gave lower TVFR0.5 values, more negative SVFR values, and a reduction in total SOA production. The radical conditions were changed by introducing OH scavengers to generate systems with and without OH radicals and with different [HO2]/[RO2] ratios. The presence of a scavenger and lower [HO2]/[RO2] ratio reduced SOA production. Observed changes in SVFR values could be linked to the more complex chemistry that occurs in the absence of a scavenger and indicated that additional HO2 chemistry gives products with a wider range of vapor pressures. Updates to existing ozonolysis mechanisms with routes that describe the observed responses to water and radical conditions for monoterpenes with endocyclic and exocyclic double bonds are discussed.
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Watne, Ågot,1983Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology(Swepub:gu)xwatgo
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Lutz, Anna,1986Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology(Swepub:gu)xlutan
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Ljungström, Evert,1949Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology(Swepub:gu)xljune
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Hallquist, Mattias,1969Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology(Swepub:gu)xhamat
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Göteborgs universitetInstitutionen för kemi och molekylärbiologi
(creator_code:org_t)
Related titles
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In:Journal of Physical Chemistry A: American Chemical Society (ACS)117:40, s. 10346-103581089-56391520-5215
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