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Transient two-dimen...
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Panman, Matthijs R,1983Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology
(författare)
Transient two-dimensional vibrational spectroscopy of an operating molecular machine
- Artikel/kapitelEngelska2017
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2017-12-20
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Springer Science and Business Media LLC,2017
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LIBRIS-ID:oai:gup.ub.gu.se/264610
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https://gup.ub.gu.se/publication/264610URI
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https://doi.org/10.1038/s41467-017-02278-6DOI
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Synthetic molecular machines are promising building blocks for future nanoscopic devices. However, the details of their mechanical behaviour are in many cases still largely unknown. A deeper understanding of mechanics at the molecular level is essential for the design and construction of complex nanodevices. Here, we show that transient two-dimensional infrared (T2DIR) spectroscopy makes it possible to monitor the conformational changes of a translational molecular machine during its operation. Translation of a macrocyclic ring from one station to another on a molecular thread is initiated by a UV pulse. The arrival of the shuttling macrocycle at the final station is visible from a newly appearing cross peak between these two moieties. To eliminate spectral congestion in the T2DIR spectra, we use a subtraction method applicable to many other complex molecular systems. The T2DIR spectra indicate that the macrocycle adopts a boat-like conformation at the final station, which contrasts with the chair-like conformation at the initial station. © 2017 The Author(s).
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Van Dijk, C. N.
(författare)
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Huerta-Viga, A.
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Sanders, H. J.
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Bakker, B. H.
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Leigh, D. A.
(författare)
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Brouwer, A. M.
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Buma, W. J.
(författare)
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Woutersen, S.
(författare)
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Göteborgs universitetInstitutionen för kemi och molekylärbiologi
(creator_code:org_t)
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Ingår i:Nature Communications: Springer Science and Business Media LLC8:12041-1723
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