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Dissociations of wa...
Dissociations of water ions after valence and inner-valence ionization
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- Hult Roos, Andreas (author)
- Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU)
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- Eland, John H. D., 1941 (author)
- Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU)
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- Andersson, Jonas (author)
- Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU)
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- Squibb, Richard J. (author)
- Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU)
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- Feifel, Raimund (author)
- Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU)
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(creator_code:org_t)
- AIP Publishing, 2018
- 2018
- English.
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In: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 149
- Related links:
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https://gup.ub.gu.se... (primary) (free)
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https://gup.ub.gu.se...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Energy selected and mass‐resolved electron‐ion coincidence spectra of heavy water have been recorded for ionization energies from 18 to 35 eV. Dissociation from the B2B2 state produces both O+ and D2+ at energies near their thermodynamic thresholds in addition to the known products D+ and OD+. Relative yields of O+, OD+ and D+ in the B2B2 state breakdown diagram are modulated by the vibrational structure of the B‐state population, implying incomplete energy equilibration before fragmentation. Decay from the C‐state produces OD+ in addition to the known O+ and D+. The fragment kinetic energies suggest that O+ and D+ from the C state are products of full atomization of the molecule.
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Publication and Content Type
- ref (subject category)
- art (subject category)
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