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Ultrafast nuclear dynamics in the doubly-core-ionized water molecule observed via Auger spectroscopy

Marchenko, T. (author)
Sorbonne Univ, CNRS, LCPMR, F-75005 Paris, France;Synchrotron SOLEIL, Orme Merisiers, BP 48, F-91192 Gif Sur Yvette, France
Inhester, L. (author)
DESY, Ctr Free Electron Laser Sci, Notkestr 85, D-22607 Hamburg, Germany;Hamburg Ctr Ultrafast Imaging, Luruper Chaussee 149, D-22761 Hamburg, Germany
Goldsztejn, G. (author)
Sorbonne Univ, CNRS, LCPMR, F-75005 Paris, France
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Travnikova, O. (author)
Sorbonne Univ, CNRS, LCPMR, F-75005 Paris, France;Synchrotron SOLEIL, Orme Merisiers, BP 48, F-91192 Gif Sur Yvette, France
Journel, L. (author)
Sorbonne Univ, CNRS, LCPMR, F-75005 Paris, France;Synchrotron SOLEIL, Orme Merisiers, BP 48, F-91192 Gif Sur Yvette, France
Guillemin, R. (author)
Sorbonne Univ, CNRS, LCPMR, F-75005 Paris, France;Synchrotron SOLEIL, Orme Merisiers, BP 48, F-91192 Gif Sur Yvette, France
Ismail, I. (author)
Sorbonne Univ, CNRS, LCPMR, F-75005 Paris, France
Koulentianos, Dimitris, 1987 (author)
Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU),Sorbonne Univ, CNRS, LCPMR, F-75005 Paris, France;Univ Gothenburg, Dept Phys, Origovagen 6B, SE-41296 Gothenburg, Sweden
Ceolin, D. (author)
Synchrotron SOLEIL, Orme Merisiers, BP 48, F-91192 Gif Sur Yvette, France
Puttner, R. (author)
Free Univ Berlin, Fachbereich Phys, Arnimallee 14, D-14195 Berlin, Germany
Piancastelli, Maria Novella (author)
Uppsala universitet,Molekyl- och kondenserade materiens fysik,Sorbonne Univ, CNRS, LCPMR, F-75005 Paris, France
Simon, M. (author)
Sorbonne Univ, CNRS, LCPMR, F-75005 Paris, France;Synchrotron SOLEIL, Orme Merisiers, BP 48, F-91192 Gif Sur Yvette, France
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 (creator_code:org_t)
AMER PHYSICAL SOC, 2018
2018
English.
In: Physical Review A. - : AMER PHYSICAL SOC. - 2469-9926 .- 2469-9934. ; 98:6
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • We present a combined experimental and theoretical study of the Auger-emission spectrum following double core ionization and excitation of gas-phase water molecules with hard-x-ray synchrotron radiation above the O K-2 threshold. We observe an indication of ultrafast proton motion occurring within the 1.5 fs lifetime of the double-core-hole (DCH) states in water. Furthermore, we have identified symmetric and antisymmetric dissociation modes characteristic for particular DCH states. Our results serve as a fundamental reference for state-of-the-art studies of DCH dynamic processes in liquid water both at synchrotron and free-electron-laser facilities.

Subject headings

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

Keyword

x-ray
photoelectron-spectroscopy
galaxies beamline
electron

Publication and Content Type

ref (subject category)
art (subject category)

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