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Visible-Light-Drive...
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Runemark, August,1993Chalmers tekniska högskola,Chalmers University of Technology
(author)
Visible-Light-Driven Stereoselective Annulation of Alkyl Anilines and Dibenzoylethylenes via Electron Donor-Acceptor Complexes
- Article/chapterEnglish2021
Publisher, publication year, extent ...
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2021-01-05
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American Chemical Society (ACS),2021
Numbers
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LIBRIS-ID:oai:gup.ub.gu.se/303616
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https://gup.ub.gu.se/publication/303616URI
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https://doi.org/10.1021/acs.joc.0c02819DOI
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https://research.chalmers.se/publication/522263URI
Supplementary language notes
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Classification
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Subject category:ref swepub-contenttype
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Subject category:art swepub-publicationtype
Notes
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A catalyst-free, stereoselective visible-light-driven annulation reaction between alkenes and N,N-substituted dialkyl anilines for the synthesis of substituted tetrahydroquinolines is presented. The reaction is driven by the photoexcitation of an electron donor-acceptor (EDA) complex, and the resulting products are obtained in good to high yields with complete diastereoselectivity. Mechanistic rationale and photochemical characterization of the EDA-complex are provided.
Subject headings and genre
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Zacharias, Savannah C.Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology,University of Gothenburg(Swepub:gu)xzachs
(author)
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Sundén, Henrik,1978Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology,University of Gothenburg,Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)sundenh
(author)
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Chalmers tekniska högskolaInstitutionen för kemi och molekylärbiologi
(creator_code:org_t)
Related titles
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In:Journal of Organic Chemistry: American Chemical Society (ACS)86:2, s. 1901-19100022-32631520-6904
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