Search: WFRF:(Westerlund Fredrik 1978) >
Nanofluidic Trappin...
Nanofluidic Trapping of Faceted Colloidal Nanocrystals for Parallel Single-Particle Catalysis
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- Levin, Sune, 1991 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Lerch, Sarah, 1990 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Boje, Astrid, 1991 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Fritzsche, Joachim, 1977 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Kesarimangalam, Sriram, 1983 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Ström, Henrik, 1981 (author)
- Chalmers tekniska högskola,Chalmers University of Technology,Norges teknisk-naturvitenskapelige universitet (NTNU),Norwegian University of Science and Technology (NTNU)
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- Moth-Poulsen, Kasper, 1978 (author)
- Chalmers tekniska högskola,Chalmers University of Technology,Institucio Catalana de Recerca i Estudis Avancats (ICREA),Catalan Institution for Research and Advanced Studies (ICREA),Institut de Ciència de Materials de Barcelona (ICMAB-CSIC),Institute of Material Science of Barcelona (ICMAB)
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- Sundén, Henrik, 1978 (author)
- Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology,University of Gothenburg,Chalmers tekniska högskola,Chalmers University of Technology
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- Hellman, Anders, 1974 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Westerlund, Fredrik, 1978 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Langhammer, Christoph, 1978 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- 2022-09-02
- 2022
- English.
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In: Acs Nano. - : American Chemical Society (ACS). - 1936-0851 .- 1936-086X. ; 16:9, s. 15206-15214
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Abstract
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- Catalyst activity can depend distinctly on nano -particle size and shape. Therefore, understanding the structure sensitivity of catalytic reactions is of fundamental and technical importance. Experiments with single-particle resolution, where ensemble-averaging is eliminated, are required to study it. Here, we implement the selective trapping of individual spherical, cubic, and octahedral colloidal Au nanocrystals in 100 parallel nanofluidic channels to determine their activity for fluorescein reduction by sodium borohydride using fluorescence microscopy. As the main result, we identify distinct structure sensitivity of the rate-limiting borohydride oxidation step originating from different edge site abundance on the three particle types, as confirmed by first -principles calculations. This advertises nanofluidic reactors for the study of structure-function correlations in catalysis and identifies nanoparticle shape as a key factor in borohydride-mediated catalytic reactions.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi -- Annan kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Industriell bioteknik -- Biokatalys och enzymteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Industrial Biotechnology -- Biocatalysis and Enzyme Technology (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- nanoparticle trapping
- single nanoparticle catalysis
- nanofluidics
- fluorescence microscopy
- colloidal Au nanocrystals
- first-principles
- calculations
- elastic band method
- heterogeneous catalysis
- polysilsesquioxane
- dynamics
- Chemistry
- Science & Technology - Other Topics
- Materials Science
- first-principles calculations
Publication and Content Type
- ref (subject category)
- art (subject category)
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Acs Nano
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Levin, Sune, 199 ...
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Lerch, Sarah, 19 ...
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Boje, Astrid, 19 ...
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Fritzsche, Joach ...
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Kesarimangalam, ...
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Ström, Henrik, 1 ...
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Moth-Poulsen, Ka ...
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Sundén, Henrik, ...
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Hellman, Anders, ...
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Westerlund, Fred ...
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Langhammer, Chri ...
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Other Chemistry ...
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- ENGINEERING AND TECHNOLOGY
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ENGINEERING AND ...
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and Industrial Biote ...
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and Biocatalysis and ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Organic Chemistr ...
- Articles in the publication
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Acs Nano
- By the university
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University of Gothenburg
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Chalmers University of Technology