SwePub
Sök i LIBRIS databas

  Utökad sökning

WFRF:(Mellander S)
 

Sökning: WFRF:(Mellander S) > (2020-2024) > Nano structured dia...

  • Bandara, Tmwj (författare)

Nano structured diatom frustules incorporated into TiO2 photoelectrodes to enhance performance of quasi-solid-state dye-sensitized solar cells

  • Artikel/kapitelEngelska2023

Förlag, utgivningsår, omfång ...

  • 2023

Nummerbeteckningar

  • LIBRIS-ID:oai:gup.ub.gu.se/332117
  • https://gup.ub.gu.se/publication/332117URI
  • https://doi.org/10.1016/j.optmat.2023.114514DOI

Kompletterande språkuppgifter

  • Språk:engelska

Ingår i deldatabas

Klassifikation

  • Ämneskategori:ref swepub-contenttype
  • Ämneskategori:art swepub-publicationtype

Anmärkningar

  • Diatom frustules are incorporated into multilayer photoelectrodes intending to enhance efficiency in dyesensitized solar cells utilizing their light interaction properties. A specific, but ubiquitous in all oceans, pennate-type diatom frustules were used to form the composite layers. Single, double, and triple-layer photoelectrodes were constructed with pure TiO2 (control measurements) as well as with a TiO2/diatom frustule composite. The electrodes were prepared using TiO2 nanoparticles of two sizes (13 and 21 nm) and were analyzed using UV visible absorption and XRD spectra. The morphology of frustules and electrodes were analyzed using scanning electron microscopy. The performance for each photoanode configuration was measured by assembling photoelectrochemical solar cells fabricated with a Pt counter electrode and a gel polymer electrolyte that excludes volatile solvents. The efficiency of the control cell is 3.37%. After replacing the topmost TiO2 layer with a TiO2/diatom frustule composite layer, efficiency increases to 6.78%. This is an impressive efficiency enhancement of 101%. The short circuit current density of frustule-incorporated threelayer cells is 18.1 mA cm-1 while for the control cell it is 8.98 mA cm-1. The enhanced efficiency of cells made with TiO2/diatom frustule composite electrodes and a polyethylene oxide-based gel polymer electrolyte can be attributed to the improved light absorption by the photoanode due to optical scattering and light-trapping effects caused by the presence of diatom frustules. Frustules also can assist in enhancing dye adsorption by increasing the effective specific surface area of the composite photoelectrode due to their nanoporous structure.

Ämnesord och genrebeteckningar

Biuppslag (personer, institutioner, konferenser, titlar ...)

  • Withanage, S. S. (författare)
  • Wijayaratne, K. B. (författare)
  • Dissanayake, Makl (författare)
  • Bandara, Kmsp (författare)
  • Mellander, B. E. (författare)
  • Furlani, Maurizio,1958Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU) (författare)
  • Albinsson, Ingvar,1962Gothenburg University,Göteborgs universitet,Institutionen för fysik (GU),Department of Physics (GU)(Swepub:gu)xalbin (författare)
  • Göteborgs universitetInstitutionen för fysik (GU) (creator_code:org_t)

Sammanhörande titlar

  • Ingår i:Optical Materials1460925-3467

Internetlänk

Hitta via bibliotek

Till lärosätets databas

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.

 
pil uppåt Stäng

Kopiera och spara länken för att återkomma till aktuell vy