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Water Dynamics in Microemulsion Droplets. A Nuclear Spin Relaxation Study
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- Carlström, Göran (author)
- Lund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Halle, Bertil (author)
- Lund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
- (creator_code:org_t)
- 2002-05-01
- 1988
- English 7 s.
- In: Langmuir. - : American Chemical Society (ACS). - 0743-7463 .- 1520-5827. ; 4:6, s. 1346-1352
- Journal article (peer-reviewed)
Abstract
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- The state of water in aqueous microemulsion droplets in the system AOT/D2O/isooctane has been investigated by 2H and 17O NMR. Longitudinal relaxation rates are reported as a function of droplet size, droplet volume fraction, temperature, and resonance frequency. We conclude that the surface-induced perturbation of water rotation is of short range (limited to the primary hydration of the AOT head groups) and of modest magnitude (less than a factor of 10 slower rotation than in bulk water).
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
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