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Structure of two-di...
Structure of two-dimensional Fe3O4
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- Merte, Lindsay R. (författare)
- Malmö universitet,Malmö University,Institutionen för materialvetenskap och tillämpad matematik (MTM),Malmö university
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- Olsson, Pär A.T. (författare)
- Malmö universitet,Malmö University,Lund University,Lunds universitet,Mekanik,Institutionen för maskinvetenskaper,Institutioner vid LTH,Lunds Tekniska Högskola,Mechanics,Department of Mechanical Engineering Sciences,Departments at LTH,Faculty of Engineering, LTH,Institutionen för materialvetenskap och tillämpad matematik (MTM),Division of Mechanics, Lund University, Lund, 22100, Sweden,Malmö university
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- Shipilin, Mikhail (författare)
- Stockholms universitet,Stockholm University,Fysikum,Department of Physics, Stockholm University, AlbaNova University Center, 10691 Stockholm, Sweden
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- Gustafson, Johan (författare)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,Division of Synchrotron Radiation Research, Lund University, 22100 Lund, Sweden
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- Bertram, Florian (författare)
- German Electron Synchrotron (DESY),DESY Photon Science, Notkestr. 85, 22607 Hamburg, Germany,Deutsches Elektronen-Synchrotron (DESY)
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- Zhang, Chu (författare)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,Division of Synchrotron Radiation Research, Lund University, 22100 Lund, Sweden
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- Grönbeck, Henrik, 1966 (författare)
- Chalmers University of Technology,Department of Physics and Competence Centre for Catalysis, Chalmers University of Technology, 41296 Göteborg, Sweden,Chalmers tekniska högskola
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- Lundgren, Edvin (författare)
- Lund University,Lunds universitet,NanoLund: Centre for Nanoscience,Annan verksamhet, LTH,Lunds Tekniska Högskola,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Other operations, LTH,Faculty of Engineering, LTH,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH,Division of Synchrotron Radiation Research, Lund University, 22100 Lund, Sweden
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(creator_code:org_t)
- AIP Publishing, 2020
- 2020
- Engelska.
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Ingår i: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 152:11
- Relaterad länk:
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http://dx.doi.org/10...
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https://mau.diva-por... (primary) (Raw object)
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https://lup.lub.lu.s...
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https://doi.org/10.1...
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https://urn.kb.se/re...
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https://urn.kb.se/re...
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https://research.cha...
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Abstract
Ämnesord
Stäng
- We have investigated the structure of an ultrathin iron oxide phase grown on Ag(100) using surface X-ray diffraction in combination with Hubbard-corrected density functional theory (DFT+U) calculations. The film exhibits a novel structure composed of one close-packed layer of octahedrally coordinated Fe2+ sandwiched between two close-packed layers of tetrahedrally coordinated Fe3+ and an overall stoichiometry of Fe3O4. As the structure is distinct from bulk iron oxide phases and the coupling with the silver substrate is weak, we propose that the phase should be classified as a metastable two-dimensional oxide. The chemical and physical properties are potentially interesting, thanks to the predicted charge ordering between atomic layers, and analogy with bulk ferrite spinels suggests the possibility of synthesis of a whole class of two-dimensional ternary oxides with varying electronic, optical, and chemical properties.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Nanoteknik -- Nanoteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Nano-technology -- Nano-technology (hsv//eng)
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering (hsv//eng)
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