Search: (WFRF:(Matera K.)) srt2:(2010-2014) >
In Situ X-Ray Photo...
In Situ X-Ray Photoelectron Spectroscopy of Model Catalysts: At the Edge of the Gap
-
- Blomberg, Sara (author)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
-
Hoffmann, M. J. (author)
-
- Gustafson, Johan (author)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
-
show more...
-
- Martin, Natalia (author)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
-
Fernandes, V. R. (author)
-
Borg, A. (author)
-
Liu, Z. (author)
-
Chang, R. (author)
-
Matera, S. (author)
-
Reuter, K. (author)
-
- Lundgren, Edvin (author)
- Lund University,Lunds universitet,Synkrotronljusfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Synchrotron Radiation Research,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
-
show less...
-
(creator_code:org_t)
- 2013
- 2013
- English.
-
In: Physical Review Letters. - 1079-7114. ; 110:11
- Related links:
-
http://dx.doi.org/10...
-
show more...
-
https://lup.lub.lu.s...
-
https://doi.org/10.1...
-
show less...
Abstract
Subject headings
Close
- We present high-pressure x-ray photoelectron spectroscopy (HP-XPS) and first-principles kinetic Monte Carlo study addressing the nature of the active surface in CO oxidation over Pd(100). Simultaneously measuring the chemical composition at the surface and in the near-surface gas phase, we reveal both O-covered pristine Pd(100) and a surface oxide as stable, highly active phases in the near-ambient regime accessible to HP-XPS. Surprisingly, no adsorbed CO can be detected during high CO2 production rates, which can be explained by a combination of a remarkably short residence time of the CO molecule on the surface and mass-transfer limitations in the present setup. DOI: 10.1103/PhysRevLett.110.117601
Subject headings
- NATURVETENSKAP -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
Find in a library
To the university's database
- By the author/editor
-
Blomberg, Sara
-
Hoffmann, M. J.
-
Gustafson, Johan
-
Martin, Natalia
-
Fernandes, V. R.
-
Borg, A.
-
show more...
-
Liu, Z.
-
Chang, R.
-
Matera, S.
-
Reuter, K.
-
Lundgren, Edvin
-
show less...
- About the subject
-
- NATURAL SCIENCES
-
NATURAL SCIENCES
-
and Physical Science ...
-
and Atom and Molecul ...
- Articles in the publication
-
Physical Review ...
- By the university
-
Lund University