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Three-in-One C2H2-S...
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Dutta, SubhajitIndian Institute of Science Education and Research Pune
(författare)
Three-in-One C2H2-Selectivity-Guided Adsorptive Separation across an Isoreticular Family of Cationic Square-Lattice MOFs
- Artikel/kapitelEngelska2021
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Nummerbeteckningar
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LIBRIS-ID:oai:lup.lub.lu.se:3b800e05-5ba3-4a6b-85fd-fe7933c4090e
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https://lup.lub.lu.se/record/3b800e05-5ba3-4a6b-85fd-fe7933c4090eURI
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https://doi.org/10.1002/anie.202114132DOI
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:art swepub-publicationtype
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Ämneskategori:ref swepub-contenttype
Anmärkningar
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Energy-efficient selective physisorption driven C2H2 separation from industrial C2-C1 impurities such as C2H4, CO2 and CH4 is of great importance in the purification of downstream commodity chemicals. We address this challenge employing a series of isoreticular cationic metal-organic frameworks, namely iMOF-nC (n=5, 6, 7). All three square lattice topology MOFs registered higher C2H2 uptakes versus the competing C2-C1 gases (C2H4, CO2 and CH4). Dynamic column breakthrough experiments on the best-performing iMOF-6C revealed the first three-in-one C2H2 adsorption selectivity guided separation of C2H2 from 1:1 C2H2/CO2, C2H2/C2H4 and C2H2/CH4 mixtures. Density functional theory calculations critically examined the C2H2 selective interactions in iMOF-6C. Thanks to the abundance of square lattice topology MOFs, this study introduces a crystal engineering blueprint for designing C2H2-selective layered metal-organic physisorbents, previously unreported in cationic frameworks.
Ämnesord och genrebeteckningar
Biuppslag (personer, institutioner, konferenser, titlar ...)
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Mukherjee, SoumyaIndian Institute of Science Education and Research Pune,Technical University of Munich
(författare)
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Qazvini, Omid T.University of Manchester
(författare)
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Gupta, Arvind K.Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)ar2207gu
(författare)
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Sharma, ShivaniIndian Institute of Science Education and Research Pune
(författare)
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Mahato, DebanjanIndian Institute of Science Education and Research Pune
(författare)
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Babarao, RavichandarCommonwealth Scientific and Industrial Research Organisation (CSIRO),RMIT University
(författare)
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Ghosh, Sujit K.Indian Institute of Science Education and Research Pune
(författare)
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Indian Institute of Science Education and Research PuneTechnical University of Munich
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Angewandte Chemie - International Edition: Wiley1433-78511521-3773
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