Reversible hydrogen storage in NaF-Al composites

• This work demonstrates that hydrogen can be reversibly stored in a composite of NaF and Al. NaF and Al reacts to a mixture of Na3AlF6 and NaAlH4 via hydridofluoride phases of the form Na3AlH6-xFx. The analysis of thermodynamics based on literature standard enthalpies of formation yields the technically favourable enthalpy of reaction of roughly 35 kJ/mol H-2 for a theoretical gravimetric hydrogen storage capacity of 3.3 wt%. Reaction mechanisms are discussed with respect to substitution of hydrogen by fluorine in complex hydrides. (C) 2008 Elsevier B.V. All rights reserved.

Subject headings

NATURVETENSKAP  -- Fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences (hsv//eng)

Keyword

Hydrogen storage materials

Milling

X-ray diffraction

diffraction

Neutron

Calorimetry

Publication and Content Type

art (subject category)

ref (subject category)